In Situ Vitrification

by Edward Behm, Matthew Gross, Dan Quesenberry, & Dan Vipperman

Spring 1997




Table of Contents 


  1. What is In Situ Vitrification?
  2. The process of In Situ Vitrification.
  3. The Advantages of In Situ Vitrification.
  4. Value of In Situ Vitrification to Soil & Groundwater Remediation.


What is In Situ Vitrification? 
 In Situ Vitrification is a new technology developed for a new nastier breed of contaminants and pollutants.  "In Situ" means to work in place.  "Vitrification" is the process to make glass out of something.  The relevant meaning of "In Situ Vitrification" in respect to soil and groundwater pollution is to turn the soil containing the pollutant into a large block of glass.  The pollutant can then be left in place forever encased inside of the glass.  A normal site undergoing in Situ Vitrification looks like the following.
Diagram drawn by Edward Behm. 
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The Process of In Situ Vitrification. 
The first part of the procedure for using In Situ Vitrification is determining the type of pollutants in the ground.  After the determination of what type of pollutant is involved the decision to use in situ vitrification can be made.  In Situ Vitrification utilizes 4 large graphite electrodes that are inserted into the ground in a square pattern.  The Vitrification depth is limited by the length of the graphite electrodes and the availability of power.  As the electrodes are driven into the ground, powerful generators or a direct line to a city power grid are activated.  The electricity arcs from one electrode to another.  As the electricity passes through the soil great heat is produced.  This heat reduces the soil into a molten form.  As the ground liquefies the electrodes move deeper, increasing the amount of molten soil.  When the graphite electrodes have reached the maximum possible depth the electricity is shut off and the electrodes are disconnected from the system.  As the molten soil solidifies into glass the graphite electrodes become entombed. The temperatures achieved by In Situ Vitrification have reached temperatures ranging from 1,600 to 1,800 degrees Celcius. Individual blocks of glass have been formed as large as 1,400 tons and depths exceeding 20-ft have been achieved. Adjacent processes can fuse the vitrified blocks together to form a single contiguous monolith.

The pollutants react in various ways to this remediation technique.  Organic pollutants are pyrolyzed and are generally reduced into gasses.  The gasses rise to the surface where they are collected by a gas hood over the affected site.  The gases are then transported to an off-gas treatment center.  This is a treatment system for the rendering volatile or dangerous gasses from the vitrification process inert.  The inorganic pollutants or heavy metals are encased in the glass formed by the vitrification process.  Radioactive materials are also encased in the glass and the glass formed by the soil also helps to limit the radiation leakage.   During the molten phase of the process almost all of the void spaces in the soil are removed and therefore there is a volume reduction of 20-50%.  This results in a very dense block of glass.
drawn by Edward Behm 
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The Advantages of In Situ Vitrification. 
There are many advantages to In Situ Vitrification over other conventional remediation techniques.

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Value of In Situ Vitrification to Soil and Groundwater Remediation. 
The Insitu vtrification process can have several advantages over other remediation processes or the removing of the pollutant in question.  Below is a list of these advantages:

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References

  1. Hanson, James.  "Geosafe In Situ Vitrification Site Demonstration"  Geosafe Corporation, 31 Mar 95. http://128.6.70.23/html_docs/rrd/hansen.html
  2. Tixier, John.  "In Situ Vitrification"  Pacific Northwest Corporation,  13 Apr 96.  http://www.em.doe.gov/rainland/land49.html
  3. Nemeth, John. "Environmental Applications Research and Future Plans in Plasma Arc Technology at the Georgia Institute of Technology" Georgia Tech Research Corporation, 26 Sep 96. http://eoeml-www.gtri.gatech.edu/lab/nemeth_paper.html
  4. Richardson, Terry. "In Situ Vitrification Treats Organics and Inorganics" Risk Reduction Engineering Laboratory of the U.S. Environmental Protection Agency, November 1995.  http://clu-in.com/ttvitrif.htm




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Student Authors:
    Matthew Gross (mgross@vt.edu) Editor in charge of HTML format and Text Editor
    Edward Behm (ebehm@vt.edu) Graphics Artist
    Dan Quesenberry (dquesenb@vt.edu)  Text Editor
    Dan Vipperman (dvipperm@vt.edu) Text Editor
Faculty Advisor: Dr. Persuad (npers@vt.edu)
Copyright © 1998 Daniel Gallagher (dang@vt.edu)
Last Modified: June 7, 1998